Location

Academic Pit

Advisor(s)

Dr. M. V. Reddy

Mr Phua William

Start Date

30-6-2018 11:20 AM

End Date

30-6-2018 11:35 AM

Abstract

Lithium ion batteries (LIBs) are commonly found in many portable electronic appliances due to their ability to be rechargeable. Currently, commercial anodes in Li-ion batteries (graphite) have a theoretical capacity of around 372 mAh/g, while FeCo2O4 that will be investigated as the anode material has a theoretical capacity of 901.985mAh/g, more than double of the current commercial anode’s capacity. Earlier work done by Sharma et al also showed that FeCo2O4 has a very promising initial capacity of 827mAh/g. As such, the engineering goal is to produce a battery that will have a higher capacity than the current commercial Li-ion batteries through increasing the capacity of the anode material. The molten salt method and the citric acid combustion method were used to synthesise the anode active material as they are of lower cost. SEM and XRD analysis showed that FeCo2O4 synthesised by the Molten Salt Method (MSM) was of a higher purity than that synthesised by the Citric Acid Combustion Method (CAC). This further supports our findings that FeCo2O4 synthesised by the MSM has a higher cyclic stability than the one synthesised by CAC. However, both samples reflected a high capacity fade and resistance to charge transfer.

Comments

Recipient of the Most Innovative Research Award

Share

COinS
 
Jun 30th, 11:20 AM Jun 30th, 11:35 AM

FeCo2O4 as an Anode Material for Lithium Ion Batteries

Academic Pit

Lithium ion batteries (LIBs) are commonly found in many portable electronic appliances due to their ability to be rechargeable. Currently, commercial anodes in Li-ion batteries (graphite) have a theoretical capacity of around 372 mAh/g, while FeCo2O4 that will be investigated as the anode material has a theoretical capacity of 901.985mAh/g, more than double of the current commercial anode’s capacity. Earlier work done by Sharma et al also showed that FeCo2O4 has a very promising initial capacity of 827mAh/g. As such, the engineering goal is to produce a battery that will have a higher capacity than the current commercial Li-ion batteries through increasing the capacity of the anode material. The molten salt method and the citric acid combustion method were used to synthesise the anode active material as they are of lower cost. SEM and XRD analysis showed that FeCo2O4 synthesised by the Molten Salt Method (MSM) was of a higher purity than that synthesised by the Citric Acid Combustion Method (CAC). This further supports our findings that FeCo2O4 synthesised by the MSM has a higher cyclic stability than the one synthesised by CAC. However, both samples reflected a high capacity fade and resistance to charge transfer.

 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.